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List of publications (since 2017)

In press

  •  V. Brissos, P.T. Borges, F. Sancho, M.F. Lucas, C. Frazão, F. Conzuelo, L.O. Martins*, Flexible active-site loops fine-tune substrate specificity of hyperthermophilic metallo-oxidases. J. Biol. Inorg. Chem. (2024) in press. DOI: 10.1007/s00775-023-02040-y

 

2024

  •  A. Rodriguez-Abetxuko, E. Romero-Ben, A. Ontoria, M. Heredero, B. Martín-García, K. Kumar, S. Martín-Saldaña, F. Conzuelo, A. Beloqui*, Engineered metal-loaded biohybrids to promote the attachment and electron-shuttling between enzymes and carbon electrodes. Adv. Funct. Mater. (2024), 2400479. DOI: 10.1002/adfm.202400479
  •  F. Rizzo, V. Brissos, S. Villain, L.O. Martins, F. Conzuelo*, Simple and directed immobilization of a multicopper oxidase on flat bare gold electrodes provides high catalytic currents for O2 reduction. ACS Catal. (2024) 14, 4760–4767. DOI: 10.1021/acscatal.4c00516
  •  G. Moro, A. Silvestri, A. Ulrici, F. Conzuelo, C. Zanardi*, How to optimize the analytical performance of differential pulse voltammetry: one variable at time versus Design of Experiments. J. Solid State Electrochem. (2024) 28, 1403-1415. DOI: 10.1007/s10008-023-05753-x

 

2023

  •  G. Moro, V. Brissos, C. Zanardi, L.O. Martins, F. Conzuelo*, Electrochemical investigations of the multicopper oxidase from Aquifex aeolicus under direct electron transfer with carbon electrodes. Electrochim. Acta (2023) 468, 143199. DOI: 10.1016/j.electacta.2023.143199
  •  P. Wang, A. Frank, J. Appel, M. Boehm, N. Strabel, M.M. Nowaczyk, W. Schuhmann*, F. Conzuelo*, K. Gutekunst*, In vivo assembly of photosystem I-hydrogenase chimera for in vitro photoH2 production. Adv. Energy Mater. (2023) 13, 2203232. DOI: 10.1002/aenm.202203232
  •  P. Wang, A. Frank, F. Zhao, M.M. Nowaczyk, F. Conzuelo*, W. Schuhmann*, A biomimetic assembly of folded photosystem I monolayers for an improved light utilization in biophotovoltaic devices. Bioelectrochemistry (2023) 149, 108288. DOI: 10.1016/j.bioelechem.2022.108288

 

2022

  •  J.M. Becker, A. Lielpetere, J. Szczesny, J.R.C. Junqueira, P. Rodríguez-Maciá, J.A. Birrell, F. Conzuelo*, W. Schuhmann*, Bioelectrocatalytic CO2 reduction by redox polymer-wired carbon monoxide dehydrogenase gas diffusion electrodes. ACS Appl. Mater. Interfaces (2022) 14, 46421–46426. DOI: 10.1021/acsami.2c09547
  •  Frank, F. Conzuelo, W. Schuhmann, M.M. Nowaczyk*, Light-driven in vitro catalysis with photosynthetic biohybrids | Lichtgetriebene in vitro-Katalyse mit photosynthetischen Biohybriden. BIOspektrum (2022) 28, 546–548. DOI: 10.1007/s12268-022-1808-4
  •  Z. Herrero-Medina, P. Wang, A. Lielpetere, A.S. Bashammakh, A.O. Alyoubi, I. Katakis*, F. Conzuelo*, W. Schuhmann*, A biophotoelectrode based on boronic acid-modified Chlorella vulgaris cells integrated within a redox polymer. Bioelectrochemistry (2022) 146, 108128. DOI: 10.1016/j.bioelechem.2022.108128
  •  F. Zhao, A.C. Brix, A. Lielpetere, W. Schuhmann*, F. Conzuelo*, On the mediated electron transfer of immobilized galactose oxidase for biotechnological applications. Chem. Eur. J. (2022) 28, e202200868. DOI: 10.1002/chem.202200868
     Front cover and Journal cover profile: Chem. Eur. J. (2022) e202201306
  •  J.M. Becker, A. Lielpetere, J. Szczesny, A. Ruff, F. Conzuelo, W. Schuhmann*, Assembling a low-volume biofuel cell on a screen-printed electrode for glucose sensing. Electroanalysis (2022) 34, 1629–1637. DOI: 10.1002/elan.202200084
  •  Lielpetere, J.M. Becker, J. Szczesny, F. Conzuelo, A. Ruff, J. Birrell, W. Lubitz, W. Schuhmann*, Enhancing the catalytic current response of H2 oxidation gas diffusion bioelectrodes using an optimized viologen-based redox polymer and [NiFe] hydrogenase. Electrochem. Sci. Adv. (2022) 2, e2100100. DOI: 10.1002/elsa.202100100

 

2021

  •  P. Wang, F. Zhao, A. Frank, S. Zerria, A. Lielpetere, A. Ruff, M.M. Nowaczyk, W. Schuhmann*, F. Conzuelo*, Rational design of a photosystem I photoanode for the fabrication of biophotovoltaic devices. Adv. Energy Mater. (2021) 11, 2102858. DOI: 10.1002/aenm.202102858
  •  S. Dieckhöfer, D. Medina, A. Ruff, F. Conzuelo, W. Schuhmann*, Pseudocapacitive redox polymers as battery materials: A proof-of-concept all-polymer aqueous battery. ChemElectroChem (2021) 8, 2308–2314. DOI: 10.1002/celc.202100450
  •  A.F. Quintero-Jaime, F. Conzuelo*, W. Schuhmann, D. Cazorla-Amorós, E. Morallón*, Multi-wall carbon nanotubes electrochemically modified with phosphorus and nitrogen functionalities as a basis for bioelectrodes with improved performance. Electrochim. Acta (2021) 387, 138530. DOI: 10.1016/j.electacta.2021.138530
  •  A.F. Quintero-Jaime, F. Conzuelo*, D. Cazorla-Amorós, E. Morallón*, Pyrroloquinoline quinone-dependent glucose dehydrogenase bioelectrodes based on one-step electrochemical entrapment over single-wall carbon nanotubes. Talanta (2021) 232, 122386. DOI: 10.1016/j.talanta.2021.122386
  •  P. Wang, A. Frank, F. Zhao, J. Szczesny, J.R.C. Junqueira, S. Zacarias, A. Ruff, M.M. Nowaczyk, I.A.C. Pereira, M. Rögner, F. Conzuelo*, W. Schuhmann*, Closing the gap for electronic short-circuiting: Photosystem I mixed monolayers enable improved anisotropic electron flow in biophotovoltaic devices. Angew. Chem. Int. Ed. (2021) 60, 2000–2006. DOI: 10.1002/anie.202008958
  •  O.A. Krysiak, J.R.C. Junqueira, F. Conzuelo, T. Bobrowski, J. Masa, A. Wysmolek, W. Schuhmann*, Importance of catalyst-photoabsorber interface design configuration on the performance of Mo-doped BiVO4 water splitting photoanodes. J. Solid State Electrochem. (2021) 25, 173–185. DOI: 10.1007/s10008-020-04636-9

 

2020

  •  P. Wang, F. Zhao, V. Hartmann, M.M. Nowaczyk, A. Ruff, W. Schuhmann*, F. Conzuelo*, Reassessing the rationale behind herbicide biosensors: The case of a photosystem II/redox polymer-based bioelectrode. Bioelectrochemistry (2020) 136, 107597. DOI: 10.1016/j.bioelechem.2020.107597
  •  T. Bobrowski, F. Conzuelo, A. Ruff, V. Hartmann, A. Frank, T. Erichsen, M.M. Nowaczyk, W. Schuhmann*, Scalable fabrication of biophotoelectrodes by means of automated airbrush spray-coating. ChemPlusChem (2020) 85, 1396–1400. DOI: 10.1002/cplu.202000291
  •  J. Szczesny, J.A. Birrell, F. Conzuelo, W. Lubitz*, A. Ruff*, W. Schuhmann*, Redox-polymer-based high-current-density gas-diffusion H2-oxidation bioanode using [FeFe] hydrogenase from Desulfovibrio desulfuricans in a membrane-free biofuel cell. Angew. Chem. Int. Ed. (2020) 59, 16506–16510. DOI: 10.1002/anie.202006824
  •  M. Riedel, A. Ruff, W. Schuhmann, F. Lisdat*, F. Conzuelo*, Light-controlled imaging of biocatalytic reactions via scanning photoelectrochemical microscopy for multiplexed sensing. Chem. Commun. (2020) 56, 5147–5150. DOI: 10.1039/D0CC00777C
  •  J.S. Stefano, F. Conzuelo, J. Masa, R.A.A. Munoz, W. Schuhmann*, Coupling electrochemistry with a fluorescence reporting reaction enabled by bipolar electrochemistry. J. Electroanal. Chem. (2020) 872, 113921. DOI: 10.1016/j.jelechem.2020.113921
  •  O.A. Krysiak, J.R.C. Junqueira, F. Conzuelo, T. Bobrowski, P. Wilde, A. Wysmolek, W. Schuhmann*, Tuning light-driven water oxidation efficiency of molybdenum-doped BiVO4 by means of multicomposite catalysts containing nickel, iron, and chromium oxides. ChemPlusChem (2020) 85, 327–333. DOI: 10.1002/cplu.201900701
  •  Ruff, F. Conzuelo, W. Schuhmann*, Bioelectrocatalysis as the basis for the design of enzyme-based biofuel cells and semi-artificial biophotoelectrodes. Nat. Catal. (2020) 3, 214–224. DOI: 10.1038/s41929-019-0381-9
  •  O.A. Krysiak*, G. Cichowicz, F. Conzuelo, M.K. Cyranski, J. Augustynski, Ni-Fe-Cr-oxides: an efficient catalyst activated by visible light for the oxygen evolution reaction. Z. Phys. Chem. (2020) 234, 633–643. DOI: 10.1515/zpch-2019-1431

 

2019

  •  F. Zhao, P. Wang, A. Ruff, V. Hartmann, S. Zacarias, I.A.C. Pereira, M.M. Nowaczyk, M. Rögner, F. Conzuelo*, W. Schuhmann*, A photosystem I monolayer with anisotropic electron flow enables Z-scheme like photosynthetic water splitting. Energy Environ. Sci. (2019) 12, 3133–3143. DOI: 10.1039/C9EE01901D
  •  C.S. Santos, F. Conzuelo, V. Eßmann, M. Bertotti, W. Schuhmann*, Enhanced sensitivity of scanning bipolar electrochemical microscopy for O2 detection. Anal. Chim. Acta (2019) 1087, 36–43. DOI: 10.1016/j.aca.2019.08.049
  •  F. Mariani, F. Conzuelo, T. Cramer*, I. Gualandi, L. Possanzini, M. Tessarolo, B. Fraboni, W. Schuhmann*, E. Scavetta*, Microscopic determination of carrier density and mobility in working organic electrochemical transistors. Small (2019) 15, 1902534. DOI: 10.1002/smll.201902534
  •  F. Zhao, T. Bobrowski, A. Ruff, V. Hartmann, M.M. Nowaczyk, M. Rögner, F. Conzuelo*, W. Schuhmann*, A light-driven Nernstian biosupercapacitor. Electrochim. Acta (2019) 306, 660–666. DOI: 10.1016/j.electacta.2019.03.168
  •  S. Alsaoub, F. Conzuelo, S. Gounel, N. Mano, W. Schuhmann*, A. Ruff*, Introducing pseudocapacitive bioelectrodes into a biofuel cell/biosupercapacitor hybrid device for optimized open circuit voltage. ChemElectroChem (2019) 6, 2080–2087. DOI: 10.1002/celc.201900256
  •  F. Zhao, A. Ruff, M. Rögner, W. Schuhmann*, F. Conzuelo*, Extended operational lifetime of a photosystem-based bioelectrode. J. Am. Chem. Soc. (2019) 141, 5102–5106. DOI: 10.1021/jacs.8b13869
  •  S. Barwe, C. Andronescu*, R. Engels, F. Conzuelo, S. Seisel, P. Wilde, Y.-T. Chen, J. Masa, W. Schuhmann*, Cobalt metalloid and polybenzoxazine derived composites for bifunctional oxygen electrocatalysis. Electrochim. Acta (2019) 297, 1042–1051. DOI: 10.1016/j.electacta.2018.12.047
  •  N. Marković, F. Conzuelo, J. Szczesny, M.B. González García, D. Hernández Santos, A. Ruff, W. Schuhmann*, An air-breathing carbon cloth-based screen-printed electrode for applications in enzymatic biofuel cells. Electroanalysis (2019) 31, 217–221. DOI: 10.1002/elan.201800462

 

2018

  •  J. Szczesny, N. Marković, F. Conzuelo, S. Zacarias, I.A.C. Pereira, W. Lubitz, N. Plumeré, W. Schuhmann*, A. Ruff*, A gas breathing hydrogen/air biofuel cell comprising a redox polymer/hydrogenase-based bioanode. Nat. Commun. (2018) 9, 4715. DOI: 10.1038/s41467-018-07137-6
  •  F. Zhao, V. Hartmann, A. Ruff, M.M. Nowaczyk, M. Rögner, W. Schuhmann*, F. Conzuelo*, Unravelling electron transfer processes at photosystem 2 embedded in an Os-complex modified redox polymer. Electrochim. Acta (2018) 290, 451–456. DOI: 10.1016/j.electacta.2018.09.093
  •  F. Conzuelo, A. Schulte, W. Schuhmann*, Biological imaging with scanning electrochemical microscopy. Proc. R. Soc. A (2018) 474, 20180409. DOI: 10.1098/rspa.2018.0409
  •  Ruff*, J. Szczesny, N. Marković, F. Conzuelo, S. Zacarias, I.A.C. Pereira, W. Lubitz, W. Schuhmann*, A fully protected hydrogenase/polymer-based bioanode for high-performance hydrogen/glucose biofuel cells. Nat. Commun. (2018) 9, 3675. DOI: 10.1038/s41467-018-06106-3
     Research highlight in Nat. Catal. (2018) 1, 736 
  •  F. Conzuelo*, N. Marković, A. Ruff, W. Schuhmann*, The open circuit voltage in biofuel cells: Nernstian shift in pseudocapacitive electrodes. Angew. Chem. Int. Ed. (2018) 57, 13681–13685. DOI: 10.1002/anie.201808450
  •  F. Conzuelo*, A. Ruff*, W. Schuhmann*, Self-powered bioelectrochemical devices. Curr. Op. Electrochem. (2018) 12,156–163. DOI: 10.1016/j.coelec.2018.05.010
  •  G. Saper+, D. Kallmann+, F. Conzuelo, F. Zhao, T.N. Tóth, V. Liveanu, S. Meir, J. Szymanski, A. Aharoni, W. Schuhmann, A. Rothschild, G. Schuster*, N. Adir*, Live cyanobacteria produce photocurrent and hydrogen using both the respiratory and photosynthetic systems. Nat. Commun. (2018) 9, 2168. +Equal contribution. DOI: 10.1038/s41467-018-04613-x
  •  F. Zhao, S. Hardt, V. Hartmann, H. Zhang, M.M. Nowaczyk, M. Rögner, N. Plumeré, W. Schuhmann*, F. Conzuelo*, Light-induced formation of partially reduced oxygen species limits the lifetime of photosystem 1-based biocathodes. Nat. Commun. (2018) 9, 1973. DOI: 10.1038/s41467-018-04433-z
  •  D. Jambrec, F. Conzuelo, B. Zhao, W. Schuhmann*, Potential-pulse assisted thiol chemisorption minimizes non-specific adsorptions in DNA assays. Electrochim. Acta (2018) 276, 233–239. DOI: 10.1016/j.electacta.2018.04.180

 

2017

  •  V. Eßmann, F. Zhao, V. Hartmann, M.M. Nowaczyk, W. Schuhmann*, F. Conzuelo*, In operando investigation of electrical coupling of photosystem 1 and photosystem 2 by means of bipolar electrochemistry. Anal. Chem. (2017) 89, 7160–7165. DOI: 10.1021/acs.analchem.7b01222
     Research highlight in ACS Select: J. Am. Chem. Soc. (2018) 140, 2701–2703
  •  F. Zhao, N. Plumeré, M.M. Nowaczyk, A. Ruff, W. Schuhmann*, F. Conzuelo*, Interrogation of a PS1-based photocathode by means of scanning photoelectrochemical microscopy. Small (2017) 13, 1604093. DOI: 10.1002/smll.201604093
  •  E. Vargas, F. Conzuelo, M. Ruiz, S. Campuzano, V. Ruiz-Valdepeñas Montiel, G. González de Rivera, F. López-Colino, A.J. Reviejo, J.M. Pingarrón*, Automated bioanalyzer based on amperometric enzymatic biosensors for the determination of ethanol in low-alcohol beers. Beverages (2017) 3, 22. DOI: 10.3390/beverages3020022
  •  R. Gutkowski+, C. Khare+, F. Conzuelo, Y.U. Kayran, A. Ludwig, W. Schuhmann*, Unraveling compositional effects on the light-induced oxygen evolution in Bi(V–Mo–X)O4 material libraries. Energy Environ. Sci. (2017) 10, 1213–1221. +Equal contribution. DOI: 10.1039/C7EE00287D
  •  A. Ruff+, P. Pinyou+, M. Nolten, F. Conzuelo, W. Schuhmann*, A self-powered ethanol biosensor. ChemElectroChem (2017) 4, 890–897. +Equal contribution. DOI: 10.1002/celc.201600864
  •  S. Alsaoub, A. Ruff*, F. Conzuelo, E. Ventosa, R. Ludwig, S. Shleev, W. Schuhmann*, An intrinsic self-charging biosupercapacitor comprised of a high-potential bioanode and a low-potential biocathode. ChemPlusChem (2017) 82, 576–583. DOI: 10.1002/cplu.201700114
  •  F. Zhao+, F. Conzuelo+, V. Hartmann, H. Li, S. Stapf, M.M. Nowaczyk, M. Rögner, N. Plumeré, W. Lubitz, W. Schuhmann*, A novel versatile microbiosensor for local hydrogen detection by means of scanning photoelectrochemical microscopy. Biosens. Bioelectron. (2017) 94, 433–437. +Equal contribution. DOI: 10.1016/j.bios.2017.03.037
  •  F. Conzuelo, K. Sliozberg, R. Gutkowski, S. Grutzke, M. Nebel, W. Schuhmann*, High-resolution analysis of photoanodes for water splitting by means of scanning photoelectrochemical microscopy. Anal. Chem. (2017) 89, 1222–1228. DOI: 10.1021/acs.analchem.6b03706
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